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immobilization of antioxidant on nanosilica and the aging resistance behavior in polypropylene
Chen Jing; Yang Ming Shu; Zhang Shi Min
2011
发表期刊COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
ISSN1359-835X
卷号42期号:5页码:471-477
摘要Nanosilica was firstly reacted with the reactive antioxidant, methyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate (AO), via transesterification, to form a nanosilica-immobilized antioxidant, AO-silica. And then it was incorporated into polypropylene (PP) by melt compounding. Fourier transform infrared spectroscopy combined with the other characterization methods elucidated that the reactive antioxidant was chemically immobilized onto the nanosilica surface. SEM observation showed that the nanosilica-immobilized antioxidant was homogeneously dispersed into the matrix of PP. It has been reported that the antioxidative efficiency of AO-silica was superior to the corresponding low molecular counterpart (AO), based on the measurement of the oxidation induction time (OIT) of the PP/AO-silica and the PP/AO compounds containing equivalent antioxidant component. By paying attention to the changes of carbonyl absorption at different UV exposure times, it was observed that the UV aging-resistance ability of PP/nanosilica-immobilized antioxidant was much higher than that of PP/neat nanosilica compound during the long-time accelerated photo aging. (C) 2011 Elsevier Ltd. All rights reserved.
收录类别ei,sci
关键词Nano-structures Thermal Properties Surface Analysis
部门归属Chen, Jing; Yang, Ming Shu; Zhang, Shi Min Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China. Chen, Jing Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Polymers & Composites Div, Ningbo 315201, Zhejiang, Peoples R China.
学科领域Engineering, Manufacturing ; Materials Science, Composites
语种英语
内容类型期刊论文
URI标识http://ir.iscas.ac.cn/handle/311060/14029
专题中国科学院软件研究所
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Chen Jing,Yang Ming Shu,Zhang Shi Min. immobilization of antioxidant on nanosilica and the aging resistance behavior in polypropylene[J]. COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING,2011,42(5):471-477.
APA Chen Jing,Yang Ming Shu,&Zhang Shi Min.(2011).immobilization of antioxidant on nanosilica and the aging resistance behavior in polypropylene.COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING,42(5),471-477.
MLA Chen Jing,et al."immobilization of antioxidant on nanosilica and the aging resistance behavior in polypropylene".COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING 42.5(2011):471-477.
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